Jonah J. Jameson - from the 1998 Spiderman Spider Power 2 series, this figure comes with a Daily Bugle accessory.
Black Cat - from the 1996 Spider Wars series.
Spider-Man - from the 1998 Spider Power series, he has a glowing "spider sense" eyes feature and is one of the best 5" Spidey figures ever made.
Mary Jane - from the 1999 Famouse couples two pack
Gwen Stacey - from the 1999 Marvel Silver Age series
Really appreciated Toybiz making so many members of Spider-Man's supporting cast. Wish we could have gotten a 5" Aunt May though!